The single sign-on (Azure AD Seamless SSO) feature of Azure AD adds extra value to the Azure AD authentication process and provides a better experience for your users by eliminating the need to enter passwords or even usernames whenever you need to authenticate to Azure AD to access various resources.
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Install and configure Azure AD Connect
Azure AD Connect is the replacement for DirSync and Azure AD Sync, and it in simple terms allows you to integrate your on-premises Active Directory with Azure Active Directory, keeping both directories in sync with each other. This enables you to provide identities that are consistent across your on-premises services, and services in the cloud such as Office 365, or other SaaS applications without the need for separate logon credentials to private and public cloud resources.